| 학회 |
한국화학공학회 |
| 학술대회 |
2015년 가을 (10/21 ~ 10/23, 일산 KINTEX) |
| 권호 |
21권 2호, p.2224 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
CuMgCrAl oxides Catalyst for Hydrogenolysis of Glycerol to 1,2-Propandiol |
| 초록 |
Glycerol is obtained as a by-product in Biodiesel Synthesis and it can be converted into many value-added chemicals. One such reaction is 1,2-propanediol(1,2-PDO) obtained by hydrogenolysis of glycerol with an acid or base catalyst. In the present work, effect of ratio of Cr/Al was studied respectively 0.2, 0.5 1, 1.5, and 1.8. The hydrotalcite-like catalysts were prepared by coprecipitation method and calcined at 900 ℃. All prepared catalysts were characterized by N2 physisorption, XRD, SEM, TPR and TPD. Hydrogenolysis of glycerol reaction was carried out in the fixed bed down flow reactor at 190 ℃, 25 bar pressure. With Cr/Al ratio = 1, CuCr-1 catalyst 60 % glycerol conversion with 95 % selectivity towards 1,2-PDO was observed. The results shows that the structure and acidity-basicity of hydrotalcite are governed by ratio of Cr/Al. And it affects hydrogenolysis of glycerol reaction. |
| 저자 |
문동주1, 이관영2, 이승환3, 양은혁1, 정재선1, 이상용4
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| 소속 |
1KIST / UST, 2고려대, 3J&K Heaters, 4KIST / 고려대 |
| 키워드 |
Glycerol; 1; 2-Propanediol; Hydrogenolysis; Ratio of Cr/Al; Hydrotalcite-like catalyst
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| E-Mail |
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| 원문파일 |
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