| 학회 |
한국공업화학회 |
| 학술대회 |
2008년 봄 (05/09 ~ 05/10, 한양대학교(안산)) |
| 권호 |
12권 1호 |
| 발표분야 |
촉매 |
| 제목 |
Kinetic resolution of terminal epoxides with phenols catalyzed by (salen) Co-BF3 immobilized on meso/ micro porous silicates |
| 초록 |
A route to synthesize porous materials with a meso/ microscopic pore system has been investigated in this work. These meso/ micro porous structured silicates have been applied as a support in the kinetic resolution of epichlorohydrine with phenol to synthesize optically pure α-arloxy alcohols. The catalyst has been prepared by immobilization of (Salen) Co-BF3 on MCM-41, MCM-48, and on the surface of SiO2. The immobilized salen catalysts showed a high enantioselectivity in the kinetic resolution. |
| 저자 |
라울, 김용석, 곽소봉, 김건중
|
| 소속 |
인하대 |
| 키워드 |
Immobilization; Kinetic resolution; cobalt salen; MCM-41; MCM-48.
|
| E-Mail |
|
