화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터)
권호 15권 1호, p.516
발표분야 에너지
제목 The Spectroscopy Analysis of the Hydroquinone Clathrate
초록 Hydroquinone is a known clathrate former with guest molecules such as methane or xenon. Hydroquinone crystallize into three common structures: alpha(α), beta(β) and beta(β)-empty. The clathrate phase (β phase) of HQ has cavities composed of six hydroquinone molecules terminated at the top and bottom by rings of six hydroxyl groups. These cavities have a radius of about 4.5 .
In the current work we research a structural transformation of HQ. In addition to the structural information from the XRD data, Raman spectroscopic data confirms the presence of guest gas such as carbon dioxide, methane, hydrogen contained within β-HQ or β-empty HQ clathrate lattice.
저자 한규원
소속 한국해양대
키워드 hydroquinone; hydrogen; raman; carbon dioxide
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