화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 고분자합성
제목 Synthesis of poly(PU-co-SMA) copolyemer by amidization and imidization from PU prepolymer and SMA
초록 Polyurethane (PU) is one of the versatile polymers that have been widely used in various fields such as foams, coating, adhesives, rubbers and thermoplastic elastomers. Poly(styrene-co-maleic anhydride) (SMA) has excellent properties, including good heat resistance and adjustable compatibility with styrenic polymers and polar polymers. Futhermore, maleic anhydride groups (MnA) in SMA can be used for modification of SMA backbone to improve its thermal and mechanical properties. In this study, poly(PU-co-SMA) (P-SMA) was synthesized through ring opening reaction of MnA in SMA with isocyanate groups of PU prepolymer. It is postulated that the introduction of amide and imide groups on PU backbone can largely enhance the thermal and mechanical properties of PU.
저자 이상협, 이대수
소속 전북대
키워드 styrene maleic anhydride; polyurethane prepolymer
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