화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2005년 가을 (10/28 ~ 10/29, 건국대학교)
권호 9권 2호
발표분야 정밀화학
제목 New Synthetic Method for a,b-Bis(trichlorosilyl)alkanes. Double Silylation of Olefins with Trichlorosilane in the Presence of tetrabutylphosphonium chloride
초록

Reaction of olefins such as styrene, terminal and internal alkenes with trichlorosilane in the presence of tetrabutylphosphonium chloride as a catalyst at 180 oC gave the bis-silylation products, bis(chlorosilyl)alkanes, in fair to excellent yields (43 - 86%) depending upon the olefin substituents.
저자 임원철, 한준수, 강승현, 유복렬
소속 한국과학기술(연)
키워드 Bis(silyl)methanes; Si–C coupling; trichlorosilane
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