| 학회 | 한국화학공학회 |
| 학술대회 | 2013년 봄 (04/24 ~ 04/26, 광주 김대중컨벤션센터) |
| 권호 | 19권 1호, p.600 |
| 발표분야 | 열역학 |
| 제목 | Vapor-liquid equilibria for binary systems of methyl phenyl carbonate, phenol, anisole and diphenyl carbonate at various pressures |
| 초록 | Polycarbonate (PC) is a durable material. Although it has high impact-resistance, it has low scratch-resistance and so a hard coating is applied to polycarbonate eyewear lenses and polycarbonate exterior automotive components. diphenylcarbonate (DPC), Dimethyl carbonate (DMC) is used as an intermediate material to PC synthesis process in the non-phosgene process. DMC is usually synthesized from CO, methanol, and O2. High-purity DMC, CO2, and water are the reaction products. In this process, when DMC reacts with phenol and bisphenol A by trans-esterification, Methylphenylcarbonate (MPC), DPC methanol to be produced. In this work, isobaric vapor–liquid equilibrium data at various pressures are reported for the MPC containg binary systems. The experimental ternary VLE data were correlated using the NRTL equation. Acknowledgement This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology.(without phosgene (2012R1A1A2008315) |
| 저자 | 신상홍, 황인찬, 박소진 |
| 소속 | 충남대 |
| 키워드 | vapor-liquid equilibria; methyl phenyl carbonate; dipheyl carbonate |
| 원문파일 | 초록 보기 |
