| 학회 |
한국화학공학회 |
| 학술대회 |
2004년 가을 (10/29 ~ 10/30, 호서대학교(아산캠퍼스)) |
| 권호 |
10권 2호, p.2294 |
| 발표분야 |
촉매/반응공학 |
| 제목 |
Selective Oxidation of Hydrogen Sulfide to Elemental Sulfur with Cu/MgO Catalyst in a Slurry Reactor |
| 초록 |
The Cu/MgO catalysts with different Cu loadings (1,4,6,15 and 30 wt%Cu) were prepared by a wet impregnation with copper nitrate as precursor. All of the catalysts were characterized by BET surface analyzer, X-ray diffraction (XRD), temperature programmed reduction (TPR). The maximum removal capacity of H2S was obtained with 4 wt% Cu/MgO catalyst, which corresponding to the highest BET surface area among the measured catalysts. The XRD of Cu/MgO catalysts showed that well dispersed Cu particles could be present on Cu/MgO with Cu loadings below 4 wt%. The crystallites of bulk CuO appeared above 6 wt% Cu/MgO, which confirmed by XRD. TPR profiles showed that the reducibility of Cu/MgO was strongly related to the loading amounts of Cu on MgO support. Therefore, the highest removal efficiency of H2S in wet oxidation could be ascribed to a good dispersion and high reducibility of Cu/MgO catalyst. |
| 저자 |
이은구1, 설용건1, 박하연2, 한지선2, 주오심3, 정광덕3
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| 소속 |
1연세대, 2이화여자대, 3한국과학기술(연) |
| 키워드 |
Cu/MgO; Removal Capacity of H2S; Dispersion
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| E-Mail |
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| 원문파일 |
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