화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 가을 (10/09 ~ 10/10, 일산킨텍스)
권호 33권 2호
발표분야 기능성 고분자
제목 Novel Organic Dye Composed of Phenothiazine and 2-cyano-2-(2,6-dimethyl-4H-pyran-4-ylidene)acetic acid for Dye-Sensitized Solar Cell Applications
초록 In recent years, great efforts have been devoted to the synthesis and property investigation of organic dyes as substitutes for the noble metal complexes in dye-sensitized solar cells. This paved a way to our research to synthesize novel organic dyes suitable for Dye-Sensitized Solar Cell Applications. 2-(2,6-bis((E)-2-(10-hexyl-10H-phenothiazin-3-yl)vinyl)-4H-pyran-4-ylidene)-2-cyanoacetic acid a novel organic dye was designed and synthesized by reacting 2-cyano-2-(2,6-dimethyl-4H-pyran-4-ylidene)acetic acid with 10-hexyl-10H-phenothiazine-3-carbaldehyde. The structure of the organic dye was established using FT-IR and 1H NMR spectroscopy. The optical properties of the dye were investigated using ultraviolet-absorption and fluorescence spectroscopy. The HOMO, LUMO and the bandgap energy were determined from the cyclic voltammetry and absorption spectroscopy. The photovoltaic properties of synthesized organic dye will be discussed.
저자 티아가라잔 산무감, 김성철, 이명진, 진성호
소속 부산대
키워드 Phenothiazine based organic dyes; Optical properties; Electrochemical Properties and DSSC.
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