| 학회 |
한국화학공학회 |
| 학술대회 |
2005년 봄 (04/22 ~ 04/23, 여수대학교) |
| 권호 |
11권 1호, p.967 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Water Gas Shift Reaction for Hydrogen Station and Fuel Processor |
| 초록 |
Water Gas Shift (WGS) reaction is one of the key catalytic stages in a fuel processor and hydrogen station. The commercial low temperature shift (LTS) catalyst (Cu-Zn/Al2O3), though highly active at low temperature, was unsuitable for commercialized applications because of the rapid deactivation tendency of the LTS catalyst under severe conditions. The Cu-Zn/Al2O3 catalyst also can not be used at temperatures above about 250℃, which further limits their utility. The WGS reaction over Pt-Ni/CeO2 catalysts was investigated to develop an alternate commercial Cu-Zn/Al2O3 catalyst. The catalyst was prepared by an impregnation method, and were characterized by N2 physisorption, CO chemisorption, XRD, TEM and TPD. It was found that Pt-Ni/CeO2 catalyst showed higher activity and stability than the commercial LTS catalyst for WGS reaction. The results suggest that Pt-Ni/CeO2 catalyst is an attractive candidate for the alternate Cu-Zn/Al2O3 catalyst for automotive applications. |
| 저자 |
류종우1, 문동주1, 이상득1, 이병권1, 안병성1, 홍석인2
|
| 소속 |
1한국과학기술(연), 2고려대 |
| 키워드 |
WGS; Pt; CeO2; LTS; Hydrogen Station; Fuel Processor
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| E-Mail |
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| 원문파일 |
초록 보기 |
