학회 |
한국공업화학회 |
학술대회 |
2012년 가을 (10/31 ~ 11/02, 대전컨벤션센터) |
권호 |
16권 2호 |
발표분야 |
포스터-석유화학.윤활유 |
제목 |
CO의 수소화를 통한 알코올 생성 반응에서 나노기공탄소지지체의 구조가 생성물에 미치는 영향 |
초록 |
The catalytic conversion of synthesis gas obtained by the gasification of coal has attracted much attention over the past few years, due to the growing demand for oxygenated products. The unique carbon monoxide adsorption behavior on Rh, Rh-based catalysts mainly supported on inorganic oxides have been applied to selectively produce C2+ oxygenates with high activity. However, methane is the most thermodynamically favorable product of the CO hydrogenation, and is unlikely to be suppressed unless the size and the dispersion of catalytic metal particles are well regulated over the support. In this study, a series of nanoporous carbon materials possessing well-ordered nanoporosity with different nanopore structures were synthesized and introduced as supports for the catalytic conversion of syngas to alcohol. The characteristics of the catalysts were scrutinized through a series of different techniques and the catalytic performance was tested in a fixed-bed reactor. |
저자 |
김민지, 김태완, 채호정, 정광은, 김철웅, 정순용
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소속 |
한국화학(연) |
키워드 |
synthesis gas; Nanoporous Carbon Supports
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E-Mail |
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