화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 37권 2호
발표분야 기능성 고분자
제목 Synthesis and characteristics of anion exchange membrane based on aminated vinylbenzyl chloride-co-styrene-co-hydroxyethyl acrylate for radox flow battery
초록 The 4-vinylbenzyl chloride(VBC)-co-styrene(St)-co-2-hydroxyethyl acrylate (HEA) copolymer (VSH) was synthesized by solution copolymerization. The quaternary ammonium groups were introduced in the VSH copolymer by amination reaction. The anion-exchange membrane, various of different crosslinking agent contents, was prepared by casting method on the glass plate. The chemical structure and thermal properties of copolymers were investigated by FT-IR, TGA and DSC. And than, the water uptake, electric resistance, ion exchange capacity and ion conductivity of anion-exchange membranes were characterized by wet method and instrumental analysis. And also, the charge-discharge efficiency of membrane was measured by Voltmeter.
저자 박성규, 황택성
소속 충남대
키워드 Anion exchange membrane; Vanadium redox flow battery; 4-vinylbenzyl chloride; Crosslinking
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