화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2012년 가을 (10/31 ~ 11/02, 대전컨벤션센터)
권호 16권 2호
발표분야 포스터-고분자
제목 Effect of crosslinking agent on the properties of quaternized 4-vinylbenzyl chloride-co-styrene-co-2-hydroxyethyl acrylate anion-exchange membrane for vanadium redox flow batteries
초록 Crosslinking density of crosslinkng agent affects performance of anion-exchange membrane. The 4-vinylbaenzyl chloride-co-styrene-co-2-hydroxyethyl acrylate copolymer (VSH) was synthesized by solution polymerization. The aminated VSH (AVSH) was synthesized by quaternarization reaction of VSH copolymer. The crosslinked AVSH membranes were prepared by glutaric acid and glutaric dialdehyde onto AVSH. The membranes properties, water uptake, ion-exchange capacity, electrical resistance, and charge-discharge performance, were measured by instrumental analysis. And then, the structure of membranes was investigated by FT-IR, GPC and NMR spectroscopy.
저자 박성규, 박희만, 황택성
소속 충남대
키워드 Anion-exchange membrane; vanadium redox flow battery; crosslinkng
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