화학공학소재연구정보센터
학회 한국화학공학회
학술대회 1999년 가을 (10/22 ~ 10/23, 경남대학교)
권호 5권 2호, p.2225
발표분야 촉매/반응공학
제목 Benzyltriethylammonium chloride를 상이동촉매로 사용하여 Bisphenol A에 의한 α, α′-Dichloro-p-xylene의 축합중합반응
초록 The polycondensation of α, α’-Dichloro-p-xylene with Bisphenol A was carriedout in the presence of benzyltriethlammonium Chloride in a two-phase system of anaqueous alkaline solution and organic solvent such as benzene. The rate ofpolycondensation was expressed as the combined terms of quaternary ammonium andreactants. The observed initial rates of polycondensation were used to analyze thepolycondensation mechanism with a cyclic phase-transfer initiation step in theheterogeneous liquid-liquid system.
저자 문보영, 이은주, 윤한수, 박상욱
소속 부산대
키워드 Polycondensation; phase-transfer catalyst; bisphenol A
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