학회 |
한국고분자학회 |
학술대회 |
2014년 가을 (10/06 ~ 10/08, 제주 ICC) |
권호 |
39권 2호 |
발표분야 |
고분자합성 |
제목 |
Non-Catalyst Polymerization of 2-Ethynylpyridine Using Perfluorobenzoyl Chloride |
초록 |
The organic semiconductors having a conjugated backbone system shows such unique properties as electrical conductivity, paramagnetism, migration and transfer of energy, color, and chemical reactivity and complex formation ability. Here, the non-catalyst polymerization method was used for the synthesis of a new ionic conjugated polymer with pentafluorobenzoyl moieties. The polymerization proceeded well to provide a high yield of polymer. The chemical structure of polymer was characterized by various instrumental methods to have a conjugated polymer backbone system with N-pentafluorobenzoylpyridinium chloride as substituents. Cyclic voltammograms of polymer exhibited the electrochemically stable window in the range of -1.25 to 1.75V. |
저자 |
제갈영순1, 진성호2, 박종욱3, 심상연4, 임권택5
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소속 |
1경일대, 2부산대, 3가톨릭대, 4강릉원주대, 5부경대 |
키워드 |
conjugated polymer; characterization; 2-ethynylpyridine; non-catalyst; photoluminescence
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E-Mail |
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