화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 고분자합성
제목 Non-Catalyst Polymerization of 2-Ethynylpyridine Using Perfluorobenzoyl Chloride
초록 The organic semiconductors having a conjugated backbone system shows such unique properties as electrical conductivity, paramagnetism, migration and transfer of energy, color, and chemical reactivity and complex formation ability. Here, the non-catalyst polymerization method was used for the synthesis of a new ionic conjugated polymer with pentafluorobenzoyl moieties. The polymerization proceeded well to provide a high yield of polymer. The chemical structure of polymer was characterized by various instrumental methods to have a conjugated polymer backbone system with N-pentafluorobenzoylpyridinium chloride as substituents. Cyclic voltammograms of polymer exhibited the electrochemically stable window in the range of -1.25 to 1.75V.
저자 제갈영순1, 진성호2, 박종욱3, 심상연4, 임권택5
소속 1경일대, 2부산대, 3가톨릭대, 4강릉원주대, 5부경대
키워드 conjugated polymer; characterization; 2-ethynylpyridine; non-catalyst; photoluminescence
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