| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
| 권호 |
19권 1호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Synthesis of a Polyacetylene Derivative by the Non-catalyst Polymerization of 2-Ethynylpyridine Using 4-(Phenylazo)benzoyl chloride |
| 초록 |
Azobenzene and its derivatives undergo cis-trans isomerization on UV irradiation. A new polyacetylene derivative was prepared by the non-catalyst polymerization of 2-ethynylpyridine using 4-(phenylazo)benzoyl chloride. The polymer structure was characterized to have a conjugated polymer backbone system with the designed azobenzene moieties.The photoluminescence spectrum showed that the PL peak is at 597 nm corresponding to the photon energy of 2.07 eV. The cyclovoltammograms of polymer exhibited the irreversible electrochemical behaviors between the oxidation and reduction peaks. |
| 저자 |
조민진1, 제갈영순2, 진성호3, 임권택4, 박종욱1
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| 소속 |
1가톨릭대, 2경일대, 3부산대, 4부경대 |
| 키워드 |
Polyacetylene; non-catalyst; azo; optical property; photoluminescence
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| E-Mail |
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