초록 |
We theoretically consider the commensurability problem of conformationally asymmetric diblock lamellar confined in nanospace with curved geometries to study how the curved surface interplaying with conformational asymmetry affect the commensurability behavior of confined diblock lamellar. Three cases of confined geometries are considered in terms of the dimensionality of confinement d. The simplest case, d=1, denotes the slit geometry such that diblock lamellar are confined in one axis (x-axis) and unconfined in the other two axes, which has been dealt with many previous theories. The case of d=2 corresponds to cylindrical confinement where the space is confined circularly in two axes (x and y axis) and unconfined in the remaining axis. Likewise, the d=3 represents spherical confinement. |