화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO))
권호 22권 1호
발표분야 무기재료_포스터
제목 Electrochemically Dealloyed NiP Catalyst for Hydrogen Evolution Reaction in Acidic Electrolyte
초록  In this study, phosphorus was introduced into Ni, which is known to have relatively high HER activity, to improve stability and performance in acidic condition. The catalyst for HER was prepared by electrodeposition on carbon paper with an electrolyte containing Ni precursor and P precursor. In addition, a certain potential was applied to the prepared catalyst to dealloy the relatively non-noble metal through selective leaching, thereby improving the high stability of the acidic condition and increasing the activity through the production of the catalyst with high surface area. All electrochemical experiments were carried out with 0.5 M H2SO4 purged with N2 for 30 min, and cyclic voltammetry was performed for performance and electrochemical surface area measurements. As a result, the catalyst prepared in this study showed high acidic resistance, high performance and large surface area.
저자 김주영, 김준형, 김현기, 안상현
소속 중앙대
키워드 hydrogen evolution reaction; electrodeposition; dealloying; nickel phosphide
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