| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
| 권호 |
37권 1호 |
| 발표분야 |
고분자합성 |
| 제목 |
Synthesis of Aliphatic Polycarbonate by Copolymerization of Carbon Dioxide with Epoxides Using Zn/Co Prussian Blue Analogues |
| 초록 |
Synthesis of polycarbonate using CO2 is one of stellar field in green chemistry because CO2 is inexpensive, nontoxic and abundant. Double metal cyanide is well-known catalyst with excellent activity for this polymerization. In this study, a new type of catalyst is investigated and used for synthesis for getting better polycarbonate’s yield and performance. The influence of the temperature on the yield, carbonate content, molecular weight is discussed. The resultant copolymers are subjected to NMR spectrum, infrared spectroscopy and gel permeation chromatography analyses |
| 저자 |
윤은수1, 김일2
|
| 소속 |
1부산대, 2합성고분자 생물접합 하이브리드 재료사업단 |
| 키워드 |
Carbon dioxide; Double metal cyanide catalysts; Epoxides
|
| E-Mail |
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