| 학회 | 한국화학공학회 |
| 학술대회 | 2005년 봄 (04/22 ~ 04/23, 여수대학교) |
| 권호 | 11권 1호, p.699 |
| 발표분야 | 열역학 |
| 제목 | Excess Molar Volumes for constituent binaries and ternary system of DMF+DBF+Formamide, NMF+DBF+Formamide and DMF+NMF+water at 298.15K |
| 초록 | Many investigations on the excess molar properties have already been carried out for binary mixtures, while that of ternary mixtures are not easily available in the literature. Especially, the excess properties for ternary mixtures, required to get insight into the nature and degree of interactions, are quite rare. DMF and NMF are well-known materials that used as selective solvent in the extraction process or extractive distillation. In spite of it, only one excess property is reported for DMF+NMF binary system and no ternary data for DMF+DBF+Formamide, NMF+DBF+ Formamide and DMF+NMF+water are found. In this work, therefore, excess molar volumes at 298.15K for the constituent binary and ternary systems of N,N-dimethylformamide(DMF), N-methylformamide(NMF), DBF(Dibutyl formamide), formamide and water mixture were determined from measured densities by using a digital tube densimeter. The experimental excess molar volumes were correlated using the Redlich-Kister polynomial. |
| 저자 | 오종혁1, 한규진2, 박소진2, Jurgen Gmehling3 |
| 소속 | 1한국원자력(연), 2충남대, 3Technische Chemie FB9 |
| 키워드 | DMF; NMF; DBF; excess property; viscosity deviation; crrelation |
| 원문파일 | 초록 보기 |
