학회 |
한국고분자학회 |
학술대회 |
2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
권호 |
41권 1호 |
발표분야 |
기능성 고분자 |
제목 |
Synthesis and characterization of sulfonated DOPO base poly(arylene ether sulfone) multiblock copolymers for fuel cell application |
초록 |
Sulfonated multiblock poly(arylene ether sulfone) copolymers containing DOPO group were prepared from the precursors of hydrophilic and hydrophobic block oligomers. The hydrophobic oligomer was prepared by 4,4’-dihydroxydiphenylsulfone and 4,4’-difluorodiphenylsulfone. And the hydrophilic oligomer prepared by DOPO and 4,4’-difluorodiphenylsulfone. Post-sulfonation process wes applied to add sulfonic acid on DOPO unit by using conc. Sulfuric acid. A series of membranes were studied by 1H-NMR spectroscopy, FT-IR, TGA, and DSC etc. The IEC and Proton conductivity of S-DOPDs were evaluated with increase of DS. |
저자 |
진정운, 김동현, 강현호, 정종언, 조광래, 이동훈
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소속 |
위덕대 |
키워드 |
fuel cell;
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E-Mail |
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