화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터)
권호 41권 1호
발표분야 기능성 고분자
제목 Synthesis and characterization of sulfonated DOPO base poly(arylene ether sulfone) multiblock copolymers for fuel cell application
초록 Sulfonated multiblock poly(arylene ether sulfone) copolymers containing DOPO group were prepared from the precursors of hydrophilic and hydrophobic block oligomers. The hydrophobic oligomer was prepared by 4,4’-dihydroxydiphenylsulfone and 4,4’-difluorodiphenylsulfone. And the hydrophilic oligomer prepared by DOPO and 4,4’-difluorodiphenylsulfone. Post-sulfonation process wes applied to add sulfonic acid on DOPO unit by using conc. Sulfuric acid. A series of membranes were studied by 1H-NMR spectroscopy, FT-IR, TGA, and DSC etc. The IEC and Proton conductivity of S-DOPDs were evaluated with increase of DS.
저자 진정운, 김동현, 강현호, 정종언, 조광래, 이동훈
소속 위덕대
키워드 fuel cell;
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