화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2003년 가을 (10/24 ~ 10/25, 한양대학교)
권호 9권 2호, p.2830
발표분야 촉매/반응공학
제목 Development of Gasoline Fuel Reformer for Fuel Cell Powered Vehicles : Ceria-based Water Gas Shift Catalysts
초록 On-board fuel processor is the most convenient method of supplying hydrogen in the absence of a suitable infrastructure for hydrogen. The WGS reaction is one of the key catalytic stages in a fuel processor. Existing commercial Cu-Zn/Al2O3 (LTS) catalyst, though highly active, was unsuitable for fuel cell powered transportation applications. The WGS reaction over Pt- and (or) Ni-containing cerium oxide catalysts was investigated to develop a high performance WGS catalyst with high stability. The thermal cycling performance over the prepared catalysts was compared with that over the commercial Cu-Zn/Al2O3 catalyst. It was found that Pt-Ni/ceria catalysts displayed reasonably good activity than Cu-Zn/Al2O3 catalyst. It was also found that Ni-Pt/ceria catalysts showed higher stability than the commercial LTS catalyst during thermal cycling test. These results suggest that the Pt-Ni/Ceria catalysts are attractive candidates for development as the alternate commercial LTS catalyst for the fuel cell powered vehicles applications.
저자 류종우1, 문동주1, 이상득1, 이병권1, 홍석인2
소속 1한국과학기술(연), 2고려대
키워드 Gasoline; Fuel Processor; WGS; Ceria; Catalyst
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