화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2018년 가을 (10/10 ~ 10/12, 경주컨벤션센터)
권호 43권 2호
발표분야 고분자합성
제목 Templated synthesis of cubic crystalline single networks having large open-space lattices by polymer cubosomes
초록 Cubic crystalline single networks of large open-space lattices are ubiquitous in nature, from biophotonic crystals to the cuticles of weevils and beetles. The biosynthesis of these structures involves the selective diffusion of chitin, in which the mechanism is not fully understood. Although synthetic equivalents of the biophotonic single networks have been pursued as metamaterials and photonic crystals, their synthesis using lipids and polymer surfactants remains elusive. In our recent study, polymer cubosomes(PCs) were the colloidal forms having the inverse cubic mesophases of block copolymers. Here we show the unique topology of PCs and suggest the synthetic method of single cubic networks utilizing PCs as templates. Our results pave the way to create synthetic cubic crystalline single networks and suggest a possible answer for how these structures are created in nature.
저자 송정은, 김경택
소속 서울대
키워드 Block copolymer; Cubosome; Template; Replica
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