화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관)
권호 34권 2호
발표분야 기능성 고분자
제목 Low band-gap Alternating Copolymers containingDonor and Acceptor Units: Synthesis and Photovoltaic Devices
초록 The concept of internal electron donoracceptor (DA) interaction has been extensively exploited to prepare low band-gap organic semiconductors. Using this strategy, new low band-gap polymers have been developed to expand the absorption spectrum to NIR range. In addition, it is generally accepted that the formation of strong intermolecular stacking is necessary to achieve high charge mobility in organic semiconductors. In order to increase the absorption wavelength and decrease the band-gap of the polymer, cyclopentadithiophene as an electron-donating units and 2,1,3-benzothiadiazole as an electron-accepting unit were employed to synthesize the polymers. We also investigated the thermal, optical and electrochemical properties of the low band-gap polymer including their possibility for electronic and optolectronic devices.
저자 이어라, Mai Ha Hoang, 김경환, 조민주, 이태완, 최동훈
소속 고려대
키워드 low band-gap polymer; organic semiconductor; photovoltaic devices
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