화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 가을 (10/11 ~ 10/12, 일산킨텍스)
권호 32권 2호
발표분야 전지기술과 고분자재료
제목 Effects of cellulose acetate on the morphology of carbonized fibers electrospun and carbonized from poly(acrylonitrile)/cellulose acetate/DMF solutions
초록 N,N-dimethylformamide(DMF) was chosen as the cosolvent of poly(acrylonitrile)(PAN) and cellulose acetate(CA). Nanofibers were prepared as the precursor of carbon nanofibers using an electrospinning set-up. The morphology of electrospun nanofibers was uneven over the whole content range. Fibers were carbonized in a tube furnace over the temperature range up to 1100oC. The surface areas of carbon fibers were investigated by automatic gas adsorption apparatus. Brunauer-Emmet-Teller(BET)-specific surface areas were measured for the carbonized nanofibers. The specific surface area was increased with increasing CA content in carbon nanofibers. When the ratio of PAN/CA in nanofibers was 3/7, the specific surface area of PAN/CA was about 4 times greater than that of pure PAN.
저자 송인규1, 김병철2
소속 1Division of Applied Chemical & Bio-Engineering, 2Hanyang Univ.
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