화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2010년 봄 (05/13 ~ 05/14, BEXCO(부산))
권호 14권 1호
발표분야 촉매
제목 Polymer-supported NHC-Cu(I) catalyst for C-S coupling Reaction: Synthesis of Raman-active Thiol containing Compounds
초록 New type of polymer-supported N-heterocyclic carbene copper (I) catalyst (PS-NHC-CuI) was developed using imidazolium with N-picolyl moieties. Various kinds of aryl sulfides were assembled efficiently with this catalyst system. Moreover, the catalyst was easily recovered from the reaction mixture by simple filtration and could be recycled with almost consistent activity. The resulting thiol containing compounds afforded unique Raman signatures that could be applied for surface-enhanced Raman scattering (SERS) labeling probes.
저자 강태규, 윤효진, 최정우, 강호만, 이윤식
소속 서울대
키워드 Heterogeneous catalyst; N-heterocyclic carbene; C-S coupling; Surface-enhanced Raman scattering
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