화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 봄 (04/29 ~ 05/01, BEXCO (부산))
권호 19권 1호
발표분야 고분자_포스터
제목 Functionalized ZrO2 nanofilled PVdF-HFP for enhanced ionic conductivity and optical transmissivity of organic-inorganic hybrid electrolyte membranes  
초록 A new electrolyte composed of functionalized ZrO2 and PVdF-HFP polymer complexed with LiCF3SO3 displayed an enhanced ionic conductivity of 1.78 × 10-3 S cm-1 and an improved optimum optical transmittance of ~70%. The increase in the electrolyte’s conductivity by 4 orders of magnitude was due to decreased polymer’s crystallinity and enhanced ionization of Li+ salt caused by ZrO2. Electrolyte’s optical transmittance increased doubly due to the reduced ZrO2 agglomeration caused by the vinyl group-containing ligand attached to ZrO2. This new hybrid electrolyte highly suits applications in the synthesis of energy efficient windows.
저자 John Marc Puguan, 김헌
소속 명지대
키워드 ZrO2; composite polymer electrolyte; electrochromic device; nanocomposite; smart windows
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