| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
20권 2호 |
| 발표분야 |
촉매_포스터 |
| 제목 |
Phosphorus-modified ordered mesoporous CoAlOx mixed oxides for product distribution during Fischer-Tropsch synthesis reaction |
| 초록 |
Fischer-Tropsch synthesis (FTS) is an alternative chemical process which can convert various carbon feedstocks into synthetic fuels via reforming process. A phosphorous-modified ordered mesoporous CoAlOx mixed oxides was prepared by using a hard-template of KIT-6 and a subsequent impregnation of phosphorous species with different contents. The phosphorous modification of mesoporous CoAlOx revealed a suppressed cobalt aluminate formation and less pronounced aggregation of cobalt particles as well. The suppressed aggregation of cobalt particles seems to be attributed to a localized presence of aluminum phosphate by forming a thermally stable metal–phosphorous oxo-species on mixed CoAlOx surfaces, which can significantly enhance the catalytic activity and structural stability of the phosphorous-modified ordered mesoporous CoAlOx under FTS reaction conditions. |
| 저자 |
박용민, 배종욱
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| 소속 |
성균관대 |
| 키워드 |
Fischer-Tropsch synthesis (FTS); ordered mesoporous CoAlOx; phosphorous modification; structural stability of CoAlOx.
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| E-Mail |
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