화학공학소재연구정보센터
학회 한국재료학회
학술대회 2014년 가을 (11/27 ~ 11/28, 대전컨벤션센터)
권호 20권 2호
발표분야 F. 광기능/디스플레이 재료(Optical Functional and Display Materials)
제목 The Effects of Annealing on P-type ZnO Thin Film with As doping
초록 ZnO thin film has been adopted for various electronic device. For making P-N junction device, n & p type ZnO formation is required. However, it is difficult to get P-type ZnO film. In this study, we demonstrated P-type ZnO thin film with As doping and investigated post annealing on ZnO film. ZnO thin film was prepared by spin coating with using zinc acetate dihydrate, monoethanolamine(MEA), 2-methoxyethanol and arsenic oxide. Film characterization includes Hall measurment, XRD, SEM and XPS.  It is confirmed that arsenic doped ZnO thin films become p type. Its carrier concentration are 3.05x1015 ~ 8.73x1015cm-3. XRD peaks shows that when arsenic was doped in ZnO, overall peak intensities of peaks are decreased. Even additional annealing does not convert the polarity of ZnO thin film, keeping p-type,  while electrical properties (ex, mobility and resistivity) of films are improved by annealing. Mobility is enhanced from 66.70 to 379.3 cm2/Vs and resistivity is decreased from 30.65 to 3.6 Ω*cm. These improvements are attributed to larger grain caused by post annealing, whicn leads to better electrica properties. Therefore, its is proposed that As doping and additional annealing could result in p-type ZnO and improvement in  electrical properties, respectively.

이 논문은 2014년도 정부(미래창조과학부)의 재원으로 한국연구재단-나노•소재기술개발사업의 지원을 받아 수행된 연구임”(2009-0082580)

 
저자 정철원, 길영인, 최창환
소속 한양대
키워드 ZnO; Doping; Mobility; Thin Film
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