화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU))
권호 20권 2호
발표분야 (전기화학) 에너지 변환/저장 장치를 위한 전기화학
제목 Hierarchical Inorganic Assemblies for Artificial Photosynthesis  
초록 Artificial photosynthesis is an attractive approach for renewable fuel generation because it offers the prospect of a technology suitable for deployment on highly abundant, non-arable land. A particular challenge is the efficient coupling of the multi-electron processes of CO2 reduction and H2O oxidation. Here, Oxo-bridged heterobinuclear units with metal-to-metal charge-transfer transitions absorbing deep in the visible act as single photon, single charge transfer pumps for driving multi-electron catalysts. A photodeposition method has been introduced for the spatially directed assembly of nanoparticle catalysts for selective coupling to the donor or acceptor metal of the light absorber. 

1. W. Kim B. A. McClure, E. Edri, H. Frei, Chem. Soc. Rev. 45, 3221 (2016)

2. W. Kim, E. Edri, H. Frei, Acc. Chem. Res. accepted (2016)  
저자 김우열
소속 숙명여자대
키워드 Artificial photosynthesis
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