| 학회 |
한국화학공학회 |
| 학술대회 |
2016년 봄 (04/27 ~ 04/29, 부산 BEXCO) |
| 권호 |
22권 1호, p.64 |
| 발표분야 |
고분자 |
| 제목 |
유무기 입도안정제 종류에 따른 열팽창 캡슐의 특성 변화 연구 |
| 초록 |
Recently, lightweight materials become a very important keyword and foaming technology is having a lot of attention from automotive industries. Thermally expandable microcapsules (TEMs) can be expanded upon heating because activation energy of liquid hydrocarbon at the core of TEMs increased at high temperature. Due to this property, TEMs are used as blowing agents or light-weight fillers in many industries. In this article, core-shell thermally expandable microcapsules were prepared via conventional and Pickering suspension polymerization. Acrylonitrile (AN) and methacrylonitrile (MAN) were used as the comonomers. The halloysite nanotubes (HNTs) and poly vinylpyrrolidon (PVP) were used as inorgarnic pickering and organic emulsifier respectively. Content of liquid hydrocarbon at the core, thermal and expanding properties of the TEM with two different emulsifiers were compared. Mechanical properties of PP foams fabricated with two different type of TEM were also analyzed. TEM polymerized with PVP provided finer expanded cell while the one fabricated with halloysite showed bigger expanded cell in PP matrix. |
| 저자 |
하진욱1, 정선경1, 황예진1, 곽성복2, 남병국3
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| 소속 |
1자동차부품(연), 2덕양산업, 3롯데케미칼 |
| 키워드 |
고분자합성 |
| E-Mail |
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| 원문파일 |
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