| 초록 |
The palladium-catalyzed Suzuki-Miyaura coupling reaction is one of the most important organic transformations for the construction of carbon-carbon bonds. Its widespread use in the synthesis of natural products, pharmaceuticals, agrochemicals, and polymers is a testament to its broad impact on the chemical science. Most Suzuki-Miyaura cross-coupling reactions are performed using palladium catalysts and the catalyst performance is largely dependent on the ligand of palladium. In this aspect, nitrogen-rich polymers have a great potential of palladium immoilized, because they have a high affinity for metals. In this study, we prepared various polymers composed of nitrogen and immobilized palladium for catalytic performance for Suzuki-miyaura cross-coupling reaction. The experimental was characterized by FT-IR, TEM, BET, SEM, GC Acknowledgments This study was supported by the National Research Foundation of Korea (grant no.: NRF-2015R1A4A1042434). |
