화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 38권 2호
발표분야 분자전자 부문위원회
제목 Side Chains Contributions to the Characteristics of Resistive Memory based on Conjugated Polyelectrolytes
초록 We investigate the effects of the structure and length of side chains on the characteristics of organic resistive memory devices with water-soluble polyfluorene (WPF) derivatives. The WPF derivatives have either an ethylene oxide (EO) or an alkyl side chain and are synthesized; the lengths of the EO side chains are 2, 4, or 6 molecules. The WPFs with the EO side chains show better memory characteristics than those with alkyl side chains of similar length. WPF-4O and WPF-hexyl show Vth values of 3 and 5 V and ON/OFF ratios of 102 and 105, respectively. The WPFs with longer EO side chains exhibit better memory characteristics than the WPF-2O with short EO side chain. The Vth values and ON/OFF ratios for WPF-2O, WPF-4O, and WPF-6O are 4, 3, and 3V, and 5 × 102, 105, and 105, respectively. The excellent switching properties of WPF-4O and WPF-6O are believed to be mainly attributed to the low trap density and highly localized current pathways.
저자 이승훈1, 오승환2, 지용성1, 김주환1, 강리라1, 김동윤1, 이세현1, Ning Lu3, 김문재4, 고흥조3, 김태욱4, 노용영1, 김동유5
소속 1광주과학기술원, 2원자력(연), 3Department of Materials Science and Engineering, 4Univ. of Texas, 5한국과학기술원
키워드 organic resistive memory; bipolar switching; ethylene oxide side chain; water-soluble polyfluorene; conjugated polyelectrolyte
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