| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
38권 2호 |
| 발표분야 |
Molecular Self-Assembly from Small Molecules and Liquid Crystals to Macromolecules |
| 제목 |
Reversible Transformation of Planar Sheets into Small Disks by Host-Guest Trigger. |
| 초록 |
A rationally-designed macrobicyclic amphiphile consisting of a hydrophilic dendron at the center of the aromatic plane self-assembles into nanoporous sheet with curved edges through the lateral association of faced dimers. These porous sheets efficiently intercalate bowl shaped-aromatic guest molecules, corannulene through the conformational inversion of the basal planes of the dimeric micelles. Notably, the intercalation of corannulene enforces the sheets to reversibly compartmentalize into the uniform disks. This switch is also accompanied by the transformation of nanopores to be closed. |
| 저자 |
김용주, 이명수
|
| 소속 |
길림대 |
| 키워드 |
self-assembly; suparmolecule; sheet
|
| E-Mail |
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