| 학회 |
한국공업화학회 |
| 학술대회 |
2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO)) |
| 권호 |
21권 2호 |
| 발표분야 |
디스플레이_포스터 |
| 제목 |
Synthesis and Photophysical Properties of Blue Phosphorescent Ir Complex with Terphenyl-Modified Phenylimidazolinate Unit |
| 초록 |
Six new cyclometalated iridium complexes of terphenyl-modified phenylimidazolinate ligands (tpim) were synthesized and characterized in order to examine the effect of bulky substituents on the structure-property relationship of these iridium complexes. Introducing bulky groups on the phenylimidazole ligand can effectively block the transition of nonradiative 3MC state and improve the emission lifetime. In order to demonstrate the bulkiness effect, X-ray single crystal structure analysis and theoretical quantum chemistry calculations were performed, and photophysical and electrochemical measurements were carried out. These results indicate that the terphenyl-phenylimidazolinato iridium complexes have potential application in fabrication deep-blue phosphorescent organic light-emitting diode devices. |
| 저자 |
윤보선, 김소연, 김진형, 강상욱, 손호진
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| 소속 |
고려대 |
| 키워드 |
Bulky substituents; long lifetime; iridium complex
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| E-Mail |
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