화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터)
권호 41권 1호
발표분야 분자전자 부문위원회 I
제목 Modification of ZnO surface using julolidine-based interfacial modifier for efficient inverted polymer solar cells
초록 To enhance the performance of inverted polymer solar cells (PSCs), we have designed and synthesized the interfacial modifiers (IMs) which provide the better surface properties of ZnO layer. The synthesized IMs were composed of electron donating and accepting parts. Julolidine or diethyl aniline was used as a donor part, and cyano acrylic acid as an acceptor part. These julolidine effects were much more powerful than the diethyl aniline: julolidine moiety significantly decreased the hydrophilicity of ZnO surface and its work function (WF). Both B1 and B2 were working well as the IMs, but B1-treated devices exhibited much higher power conversion efficiency of 8.35% than B2-treated devices (7.80%). B1 treatment on ZnO effectively reduced series resistance and leakage current in the devices due to the julolidine effects.
저자 최은영1, 남소연2, 송창은1, 공기정1, 이창진1, 정인환1, 윤성철1
소속 1한국화학(연), 2UST
키워드 interfacial modifier; cathode buffer
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