| 학회 |
한국화학공학회 |
| 학술대회 |
2017년 가을 (10/25 ~ 10/27, 대전컨벤션센터) |
| 권호 |
23권 2호, p.2155 |
| 발표분야 |
재료 |
| 제목 |
Effective Removal Mechanism of Hexavalent Chromium by Polypyrrole |
| 초록 |
The polypyrrole was studied as a hexavalent chromium adsorbent for aqueous solution. The adsorption capacity of polypyrrole was superior to those of conventional adsorbents. We investigated the adsorption mechanism behind such excellent chromate adsorption of polypyrrole, employing physical/chemical properties analyses and the pH-dependent adsorption behavior, supported by the first-principles calculation. We reveal that the pH-dependent fractional deprotonation of the pyrrolic nitrogen sites by the Jones oxidation reaction-like reaction played a pivotal role in the adsorption. |
| 저자 |
고영진1, 최근수2, 이순재3, 김희곤1, 최재우1
|
| 소속 |
1한국과학기술(연), 2울산과학기술대, 3고려대 |
| 키워드 |
화공소재 전반 |
| E-Mail |
|
| 원문파일 |
초록 보기 |
