초록 |
Robust conjugated two- (2D) and three-dimensional (3D) network polymers have attracted immense interest due to their unusual electronic, optoelectronic, magnetic and electrocatalytic properties. In addition, their tunable structures and properties promise to offer many opportunities in various applications. However, even after years of intensive exploration in science and technology, facile and scalable methods capable of producing fused-aromatic based stable 2D network polymers with uniformly decorated heteroatoms with/without holes remain limited. To overcome these issues, stable 2D organic network polymers have been designed and synthesized. Their network structures were confirmed using various characterization techniques. Furthermore, robust 3D cage-like organic network polymers have also been constructed. The results suggest that these newly-developed 2D and 3D organic network polymers offer greater opportunities, from wet-chemistry to various device applications. |