화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 고분자 가공/복합재료
제목 Synthesis of Resole Type Phenolic Microbeads by Suspension Polymerization Technique
초록 The phenolic microbeads were obtained from phenol and formaldehyde in the presence of basic catalyst by suspension polymerization. In this reaction, triethylamine and ploy(vinyl alcohol) were used as initiator and stabilizer, respectively. As crosslinking agent, haxamethylenetetramine and/or ethylene diamine were used. The phenolic microbeads were synthesized into the size within 200~1000㎛, through oligomerization and crosslinking reactions. The effects of the reaction temperature and the concentration of initiator and crosslinking agent on the size distribution and morphology of phenolic microbeads were investigated. The effects of catalyst, stabilizer, and water content on them were also examined.
저자 한동석, 김홍경
소속 충주대
키워드 Phenolic resin.; Phenolic bead; Suspension polymerization; Crosslinking agent; Polymer particles
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