| 학회 | 한국화학공학회 |
| 학술대회 | 2008년 가을 (10/23 ~ 10/24, 부산 BEXCO) |
| 권호 | 14권 2호, p.2320 |
| 발표분야 | 고분자 |
| 제목 | Preparation of Organic/Inorganic Hybrid Materials using Amphiphilic Poly(vinylidene fluoride-co-chlorotrifluoroethylene) Graft Copolymer for Fuel Cell Application |
| 초록 | A novel brush-type amphiphilic copolymer of P(VDF-co-CTFE)-g-P(SSA-co-TMSPMA) was synthesized via ATRP technique. Successful synthesis and a microphase-separated structure of the copolymer were confirmed by 1H-NMR, FT-IR spectroscopy, and TEM. This graft copolymer was combined with tetraethoxysilane at an acidic condition to produce organic-inorganic hybrid membranes through sol-gel reaction between TEOS and PTMSPMA. Upon introduction of SiO2, the proton conductivity of membranes was slightly decreased but methanol permeability was significantly decreased. The resultant nanocomposite hybrid membranes were characterized by XRD, UTM and TGA. Thermal and mechanical properties of the membranes were also slightly enhanced by the incorporation of SiO2 nanoparticles. The authors acknowledge the financial support of the Ministry of Education through the second stage Brain Korea 21 Program at Yonsei University. |
| 저자 | 고주환, 최진규, 서진아, 노동규, 김종학 |
| 소속 | 연세대 |
| 키워드 | sol-gel; ATRP; hybrid membrane; PEMFC |
| 원문파일 | 초록 보기 |
