화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터)
권호 34권 1호
발표분야 고분자 가공/복합재료
제목 Nickel-embedded carbon nanofiber composite electrodes for electrochemical supercapacitors
초록 Nickel-embedded carbon nanofiber electrodes for supercapacitor were prepared by the processes of stabilization and carbonation after electrospinning a mixture solution of nickel acetate and polyacrylonitrile in N,N-dimethylformamide. The surface morphology and structure of the composites were examined by SEM, TEM, and XRD. Compared with performances of the composite electrodes with different mass ratios of nickel and carbon by cyclic voltammetry (CV) test, the result showed that the introduction of a proper proportion of nickel into carbon nanofibers could enhance both specific capacitance and electrochemical stability. The specific capacitance of the carbon nanofiber electrode without the Ni loading was 76 F/g, while that of 20 wt.% Ni/carbon nanofiber electrode increased to 128 F/g. The improved specific capacitance might be attributed to the synergic effects from each pristine component, and the electrochemical catalysis effect of the nickel.
저자 서민강, 박수진
소속 인하대
키워드 Ni/carbon nanofiber electrodes; supercapacitor; specific capacitance; synergic effect
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