화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO))
권호 21권 2호
발표분야 석유화학윤활유_포스터
제목 Synthesis of decyl glucoside from D-glucose with 1-decanol by direct glucosidation over solid acid catalysts and its estrogenicity
초록 Synthesis of decyl glucoside was asserted over various zeolite catalysts by direct glucosidation of D-glucose. The estrogenicity of decyl glucoside was evaluated to confirm the possibility as an alternative surfactant of nonyl phenol. Catalytic properties of the microporous zeolite in the preparation of decyl glucoside from D-glucose with 1-decanol by single-step direct glucosidation. The zeolite catalysts were consisted of different acidic properties and pore topologies. The effect of acidities and pore topologies of the zeolite catalysts were discussed considering to the conversion and yields to the glucosidation. The estrogenicity of decyl glucopyranoside was estimated using E-assay method to compare that of nonylphenol. The high conversions were obtained inversely to the order of acid strength of the zeolite catalysts. The decyl glucopyranoside represented apparently lower estrogenic cell proliferation compared with nonylphenol.
저자 정상민, 이원준, 정경환, 이헌, 정상철
소속 순천대
키워드 Decyl glucoside; Endocrine disruption; Zeolite catalysts; Estrogenicity; Alternative surfactant
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