화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2007년 봄 (04/19 ~ 04/20, 울산 롯데호텔)
권호 13권 1호, p.41
발표분야 고분자
제목 Re-plasticization of Radiation-Cross-linked Polyethylene Foam Using Supercritical Fluids
초록 In this study, the re-plasticization of radiation-cross-linked polyethylene foam using supercritical fluids was investigated. The reaction was performed in a batch reactor using various supercritical fluids. The effects of parameters such as temperature, pressure, reaction time, and weight ratio of solvent to polyethylene, kind of supercritical solvent on the properties of products were investigated. The characterization of products was performed by gel fraction measurement, GPC analysis, thermal analysis and FT-IR analysis. The cross-linked polyethylene can be completely re-plasticized in the reaction temperature over 380 ℃. The molecular weight of re-plasticized products is slightly lower than that of raw linear polyethylene, but the thermal properties of polyethylene don't change so much after treatment.
저자 이홍식1, 조항규2, 황승상2, 홍순만2, 조봉규3, 송은석1, 신영호1, 이윤우1
소속 1서울대, 2한국과학기술(연), 3자원재활용기술개발사업단
키워드 supercritical; cross-linked polyethylene; re-plasticization; recycling
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