초록 |
Aggregation-induced emission (AIE) is induced to emit intensely in the aggregate and solid states. Currently, hundreds of low-mass AIE luminogens (AIEgens) have been designed and prepared. However, the luminogenic polymers with AIE characteristics, in other words, AIE-active polymers, which inherently possess good film-forming ability and amplification effect in sensing, have paid little attention. In this talk, I will first present our recent efforts on preparing AIE-active polymers by our developed alkyne-based click polymerizations, such as Cu(I)-catalyzed azide-alkyne click polymerization, spontaneous amino-yne click polymerization. The unique properties and potential applications of resultant polymers, such as photo-cross-linked and fluorescent patterns, and sensitive detection of explosives, as well as the advantages of them over low-mass AIEgens and conventional polymers will also be discussed. |