| 학회 | 한국고분자학회 |
| 학술대회 | 2004년 봄 (04/09 ~ 04/10, 고려대학교) |
| 권호 | 29권 1호, p.324 |
| 발표분야 | 의료용 고분자 부문위원회 |
| 제목 | The comparison of free radical and redox system on the surface modification of UHMWPE powder |
| 초록 | N,N-dimethyl-p-toluidine, as an accelerator under redox system was used for polymerizing MMA monomer on the temperature condition that broken the carbonyl chain of BPO and then the polymerized MMA was precoated to the surface of UHMWPE powder. SEM, UTM, FTIR-ATR, and digital thermometer were used for the mechanical, chemical, and thermal properties of the MMA surface-precoating UHMWPE powder on the two systems. It was confirmed that the mechanical properties of redox system was better than those of free radical system. This result was supposed that MMA was sufficiently wetted to the surface of UHMWPE powder on redox system. But, under redox system, the thermal properties was inferior to those of free radical system. It might be suggested that N,N-dimethyl-p-toluidine may be elevated the boiling point(90~92ºC). Acknowledgement: This work was supported by KMOWH (Grant No: IMT-2000 01-PJ11-PG9-01NT00-0011) |
| 저자 | 양대혁, 김순희, 윤관희, 이종문, 강길선 |
| 소속 | 전북대 |
| 키워드 | redox system; radical system; UHMWPE; N; N-dimethyl-p-toluidine |
