화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2016년 봄 (04/27 ~ 04/29, 부산 BEXCO)
권호 22권 1호, p.1056
발표분야 촉매 및 반응공학
제목 Effect of Oxidizer and Alkali Metal Salts on Decomposition of Ionic Liquid of Low Concentration
초록 N1,N1,N2,N2-tetramethylethane-1,2-diamine based ionic salts(TMEDA), N1,N1,N1,N2,N2, N2-hexamethylethane-1,2-diaminium dicyanamide(HMEDA-(DCA)2) was prepared following the well-known chemical reaction scheme. The chemical structure of the HMEDA-(DCA)2 was confirmed using 13C NMR spectrum and elemental analysis. The ignition delay of 40 wt% HMEDA-(DCA)2 solution was controlled to 20-100 msec dramatically using alkali metal salts, Li(CH3COO), Mg(CH3COO) and Ca(CH3COO) as a co-catalyst when white fume nitric acid was utilized as an oxidizer and also the oxidizer of low toxicity such as hydrogen peroxide was utilized.
저자 조경철, 조성준
소속 전남대
키워드 기타 촉매분야
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