| 학회 |
한국화학공학회 |
| 학술대회 |
2014년 가을 (10/22 ~ 10/24, 대전 DCC) |
| 권호 |
20권 2호, p.2424 |
| 발표분야 |
Polymer and nanotechnology symposium(고분자부문위원회) |
| 제목 |
πStructural and Optical Profiling of DNA-Coupled π-Systems |
| 초록 |
DNA-guided tri(8-hydroxyquinoline) aluminium (Alq3) microrods which is an organic conjugated semiconductor were prepared for the first time. To the best of our knowledge, there are no reports on the preparation of Alq3 microstructures with the aid of biomolecules such as DNAs as well as their optical functions. When hybridized with oligonucleotide labeled by Cy3 fluorescent dye, a significant photoluminescence variation of the Alq3 microrods was observed due to Förster resonance energy transfer (FRET), unlike when Cy5-oligonucleotide was used. Oligonucleotide-coupled 1-D Alq3 microrods studied here can be extended to applications as in organic waveguides owing to their excellent crystalline structure and optical properties generating the FRET effect. Versatile nucleotide manipulation would open up wider applications of Alq3-based materials, based on this fundamental observation. |
| 저자 |
Dong June Ahn1, Jin-Hyuk Park2, Seung-Hyuk Paik3, Chunzhi Cui4
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| 소속 |
11Department of Chemical and Biological Engineering, 2College of Engineering, 3Korea Univ. / 2KU-KIST Graduate School of Converging Science and Technology, 4Korea Univ. |
| 키워드 |
DNA; microrod; Alq3; FRET; biomolecules
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| E-Mail |
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| 원문파일 |
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