학회 |
한국화학공학회 |
학술대회 |
2009년 가을 (10/22 ~ 10/23, 일산 KINTEX) |
권호 |
15권 2호, p.2473 |
발표분야 |
나노구조 촉매 심포지엄 |
제목 |
Application of Hollow core-Shell type Mesoporous Materials in Asymmetric Catalysis |
초록 |
The deposition of hydrophilic precursor sol containing surfactants in the hydrophobic solvents onto the mono-dispersed polymer surfaces has been applied to produce the mesoporous shells after calcination. The silica hollow spheres having mesopores in the wall of shell with different macro-cavity sizes could be fabricated, and the chiral catalysts were entrapped inside of silica microcapsules or immobilized non-covalently in the pores. The catalytic activity was examined in the synthesis of chiral β-blockers or other chiral building blocks. |
저자 |
김건중 |
소속 |
인하대 |
키워드 |
chiral salen; β-blockers; mesoporous silica; hollow sphere
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