화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2009년 가을 (10/22 ~ 10/23, 일산 KINTEX)
권호 15권 2호, p.2473
발표분야 나노구조 촉매 심포지엄
제목 Application of Hollow core-Shell type Mesoporous Materials in Asymmetric Catalysis
초록 The deposition of hydrophilic precursor sol containing surfactants in the hydrophobic solvents onto the mono-dispersed polymer surfaces has been applied to produce the mesoporous shells after calcination. The silica hollow spheres having mesopores in the wall of shell with different macro-cavity sizes could be fabricated, and the chiral catalysts were entrapped inside of silica microcapsules or immobilized non-covalently in the pores. The catalytic activity was examined in the synthesis of chiral β-blockers or other chiral building blocks.
저자 김건중
소속 인하대
키워드 chiral salen; β-blockers; mesoporous silica; hollow sphere
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