화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2012년 봄 (04/25 ~ 04/27, 제주 ICC)
권호 18권 1호, p.1008
발표분야 재료
제목 Light-Emitting Electrochemical Cells Based on Phosphorescent Iridium Complex Incorporated with Ionic Liquids
초록 A heteroleptic phosphorescent iridium complex [Ir(ppz)2(dmphen)]PF6, containing 1-phenylpyrazole (ppz) as cyclometalated ligand and 5,6-dimethyl-1,10-phenanthroline (dmphen) as ancillary ligand, has been synthesized and its photophysical and electrochemical properties have been investigated. Light-emitting electrochemical cells (LECs) based on this complex were fabricated using air stable electrodes resulting in a yellowish light emission. Furthermore, three different imidazolium based ionic liquids (ILs) such as 1-butyl-3-methylimidazolium hexafluorophosphate (BMIMPF6), 1-ethyl-3-methylimidazolium hexafluorophosphate (EMIMPF6) and 1-hexyl-3-methylimidazolium hexafluorophosphate (HMIMPF6) were incorporated into the active layer and hence the luminance and the current density of the devices were found to be enhanced with increasing ionic conductivities of ILs.
저자 수네쉬 CD, 옥순성, 미둔, 문단비, 최영선
소속 부산대
키워드 iridium complex; Light-emitting electrochemical cells; ionic liquids
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