화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU))
권호 22권 2호
발표분야 환경.에너지_포스터
제목 Development of tubular divided cell by MFI-type zeolite coated ceramic tubular membrane for simultaneous generation of two electron mediators
초록 Through the tubular electrochemical reactor, a single electron mediator was generated. The present work explains two homogeneous mediators Co(III) and [Ni(I)(CN)4]3- have been generated using a tubular MFI-type zeolite coated ceramic membrane divided electrochemical cell via paired electrolysis. The electro-generation of Co(III) and [Ni(I)(CN)4]3- were achieved in highly acid and highly base pHs respectively. The achieved Co(III) and [Ni(I)(CN)4]3- concentrations by the MFI-type membrane containing tubular cell was 57% and 15%, which are equal to the commonly used Nafion324 membrane in planar arrangement. At the same time no migration of Co(II) or [Ni(II)(CN)4]2- were observed and additional results will be discussed finally.  
저자 A.G.Ramu, G. MUTHURAMAN, 문일식
소속 순천대
키워드 Zeolite tubular membrane; tubular electrochemical cell; two mediator generation; paired electrolysis
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