학회 |
한국공업화학회 |
학술대회 |
2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
권호 |
22권 2호 |
발표분야 |
환경.에너지_포스터 |
제목 |
Development of tubular divided cell by MFI-type zeolite coated ceramic tubular membrane for simultaneous generation of two electron mediators |
초록 |
Through the tubular electrochemical reactor, a single electron mediator was generated. The present work explains two homogeneous mediators Co(III) and [Ni(I)(CN)4]3- have been generated using a tubular MFI-type zeolite coated ceramic membrane divided electrochemical cell via paired electrolysis. The electro-generation of Co(III) and [Ni(I)(CN)4]3- were achieved in highly acid and highly base pHs respectively. The achieved Co(III) and [Ni(I)(CN)4]3- concentrations by the MFI-type membrane containing tubular cell was 57% and 15%, which are equal to the commonly used Nafion324 membrane in planar arrangement. At the same time no migration of Co(II) or [Ni(II)(CN)4]2- were observed and additional results will be discussed finally. |
저자 |
A.G.Ramu, G. MUTHURAMAN, 문일식
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소속 |
순천대 |
키워드 |
Zeolite tubular membrane; tubular electrochemical cell; two mediator generation; paired electrolysis
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E-Mail |
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