| 학회 |
한국화학공학회 |
| 학술대회 |
2004년 가을 (10/29 ~ 10/30, 호서대학교(아산캠퍼스)) |
| 권호 |
10권 2호, p.1322 |
| 발표분야 |
분리기술 |
| 제목 |
Pervaporation-aided Esterification of Trifluoethanol with Methacrylic Acid through New Acid-resistant PVA Membrane |
| 초록 |
For the pervaporation-aided esterification of trifluoroethanol (TFEA) with methacrylic acid (MA), new crosslinked acid-resistant PVA membranes were prepared via a crosslinking reaction between poly (vinyl alcohol) (PVA) and ethylene glycol diglycidyl ether (EGDE). For the membrane preparation, PVA/EGDE aqueous solutions were cast and thermally crosslinked to produce acid-resistant polymer networks connected with chemically stable alkyl chains and ether groups. ATR/IR and DSC observations and swelling test were used to characterize PVA membranes prepared with various contents of EGDE. The basic pervaporation properties of the membranes were investigated with TFEA/water, MA/water and pure TFEMA by varying EGDE content and operating temperature. The esterification of TFEA with MA using the PVA membranes was also carried out at a fixed reaction mixture volume and the effect of reaction temperature, catalyst content and initial molar ratio of TFEA/MA on the TFEMA conversion was investigated. |
| 저자 |
안상만1, 장봉준1, 김정훈1, 이용택2, 이수복1
|
| 소속 |
1한국화학(연), 2충남대 |
| 키워드 |
Crosslinked acid-resistant PVA membrane; Pervaporation; Esterification membrane reactor
|
| E-Mail |
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| VOD |
VOD 보기 |
| 원문파일 |
초록 보기 |
